Check your radiator carefully, are you sure there are no leaks in the radiator or hoses, secondly check the radiator cap, it's possible that the rubbers in the cap are leaking and letting steam out, is there any sign of steam escaping for example a slightly yellow-light orangish mark on the udner side of the bonnet near where the rad cap sits or around the cap on the rad itself.
I would consider 2 options, firstly have the rad cap replaced and then check for a few days, secondly have the rad serviced and checked for minor leaks.