Oh bad. Get your head gasket checked ASAP. This is critical issue respond to it accordingly. Either a previous heat up or series of heat ups due to bad cooling system (probably bad radiator) has toasted your head gasket.
Check oil level asap too and top up as required. Then drive the car with water bottles to cool off radiator along your way to garage of a good engine mechanic.
NOTE: do check if it is oil really? bcuz oil when mixed in water shows rainbow like colors. It could be simple rust too. For that change the radiator ASAP