I recently switched to running my car exclusively on high octane and seeing a 10 to 20% improvement in mileage, plus a much better pick and running.
On a full tank, with regular petrol, city would give me about 400 to 450 KM (10 to 12 KM per litre)
On a full tank with High Octane (PSO only), mileage would go to 500 - 500KM (12 to 14 KM per litre)
Regarding price difference, it used to be 15% but now in last 2 petrol bombs, the difference is 30%+ so while previously it was a net benefit, now its a 10% net loss running on HO