I concur with Samialvi.
Hi-Octane does improve the drive, with great pickup, feels like it gives more power to the engine, but only a 2 - 3 % increase in milage, which is not even noticeable.
I have tested 100% Hi-Octane at many times from CALTEX, Shell, TOTAL & PSO on a 2012 City 1300 and 2011 Cultus, but it doesn't make much of difference in mileage as compared to Super, except that it is pretty heavy on the pocket.
However, there is a major difference in fuel mileage experienced on Super from different Fuel companies.
CALTEX & TOTAL give the max mileage, whereas Shell & PSO give 15% less.
It also depends on fuel pumps and the quality of fuel they provide.
Company operated fuel pumps provide better fuel, than privately owned pumps.