I have done it, it is possible but you need to make proper shaped linsets to the back and install a block valve and a throttler to control refrigerant flow to the rear evaporator, The compressor should also be heavy duty like a Sanden 7 series at minimum. - It is not cheap or easy, on average with good new and used parts and proper fabrication - expect a cost north of Rs 60,000/- at least - including the control module for the rear unit. (this is on top of your original A/C system)
The rear unit is very expensive to come by and to install the vapor and liquid lines sensibly means that you have to completely rip out the interior of the car, get creative with bending lines and clamping them and ensuring the vapor line sweating does not cause rusting. Then installation of a split manifold and a throttler to control gas flow to both evaporators - these two items are expensive, the split valve alone is about Rs 18,000/- (2006) and is controlled by simple binary 12V signal, the throttler is required to control the flow of refrigerant so the rear expansion valve can actually work - newer climate controlled units had this done by duty cycle within one part, otherwise you might see swinging needles on the pressure gauges and no effeciency. It is also recommended to use an accumulator just in case any liquid comes along from either side..
The rear A/C box installation is not as simple as installing speakers - it requires a major chunk to be cut out from the rear shelf, this then means that you need to remove the torsion bars for the boot lid and install pulling springs like the old Galant or the mercedes W201/124/210. making some drainage holes and also insulating the box.
The rear units you will find in Pakistan are old R12 units from Crowns, Cedrics and Cressidas which stand about 4 inches high from the surface, that means that you will have nearly no visibility at the back. new cars rear screen is very sloped. You can try to rig a rear unit with ductwork into the roof with vents like an aircraft.
But all in all I think modern cars have sufficient blower volume to circulate air nicely in the entire car, just make sure the centre vents point to the roof so air actually pushes to the back of the car.
but if you are determined find an A/C place that services bus and wagon (Hiace) systems. Hiace have dual A/C units.