I once had VXR 2007 for a decade - 180k driven when i sold it.
It was really good on CNG if proper tuned, i don't remember exactly about the millage but i used to fill 500RS CNG on every trip and it was giving me around 110KM with AC in summers and around 130KM in winters in local routes (Islamabad). Good old days..........
I never filled full tank gas when drive local due to pump's nozzle calibrations issues.
Keep the car stock, remove any packing if putting in rear tyres, use stock rim with stock tyre size, keep air in tyres as per manual, I used to pour Shell CNG(yellow packing) engine oil don't remember it's exact viscosity but i always had it, 10W40 SG is might good for it. 20W50 is insane viscosity avoid it.
Don't mess with jets and carburettor stay away from these roadside mechanic's delusions, VXR heavy on petrol especially with AC in summers - without AC it's good in petrol IF tuned well on petrol settings.