See, I am not 100 % clear what you are trying to say but what I have understood is
1) Two batteries with different AMP-HR ratings have been attached in parallel configuration. Please Avoid this in future because charging rate for one may be higher and other maybe too low. End result will be, if one has been completely charged then for rest of the time it is being abused till the time second is not charged. Or one of the batteries will not be charged completely once you will be entering the next cycle of load shedding. Over period of time, one which has not be able to be charged fully will die early for remaining in discharged state for long duration and one which has been charged fully will also die early due to the overcharging abuse, it is getting. (Remember we have a frequent Load shedding)
2) 1 KVA UPS is designed to shutdown if you exceed the maximum load capacity. This is a built in feature and it should act exactly the same way. You should know the capacity of your UPS system and wirings should laid down such that Load should never exceed maximum Load for which it has been designed.
3) Obviously, you can add 200 AMP-HR battery with 1 KVA UPS as it will increase the backup time but that never says, that you can exceed the maximum load capacity, UPS has been designed for. That can damage the UPS internal wirings, transformer etc and this shutdown is a protection against this.
4) Bad Electrolyte can contribute to lesser backup time and early failure of Lead Acid batteries.
5) Anyhow all of the batteries being sold in Pakistan Market by Local Manufacturers are not designed for UPS. They are designed to provide maximum current for very short duration of time such as starting Starter Motors. Cells have larger surface Area but thinner for inside and can only be discharged till 80% before it requires charging again and die early.
Manufacturers don’t need to produce batteries solely for UPS( deep cycle batteries) once already people are buying truck batteries which die early with UPS systems. They don’t need to sweep the market once they already have a control over it. Their strategy is working, they are making money and consumers do not have an option.