your engine is running too cold, replace the thermostat with a new one, the temperature should never drop below 80C in any condition specially when driving the car.
The black smoke can be a bunch of items, this engine will smoke black for a bit on startup - like a small puff - while accelerating at full power you should not see any smoke at all unless someone took out the trap oxidiser from the exhaust. The intake manifold, charge cooler, EGR and flapper valves in the intake should be cleaned and lubed up too.
Also make sure the MAF is a genuine MB part - if someone stuck a chinese part in there or a cheap VW part - it makes the engine start and work but the engine smokes.
Start from correcting the thermostat valve and using genuine MB coolant or any DIESEL rated coolant like CAT LLC or Shell LLC. Dont use any other coolant in this car. btw - who put those large rims in there, they are not suited for this car. They even lug down an E320 (maybe I like my cars to accelerate like a bat from hell)
Use a low saps oil in this engine, namely any API CJ4 rated oil with a higher VI, make sure the engine gets real hot and toasty before you ramp on the accelerator pedal. btw this little maasoom 2.2 litre engine pushes enough torque to burn out its rear tires at the drop of a hat.